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Neptunium nitride

Chemical compound From Wikipedia, the free encyclopedia

Neptunium nitride is a binary inorganic compound of neptunium and nitrogen with the chemical formula NpN.[1][2]

Quick Facts Names, Identifiers ...
Neptunium nitride
Names
Other names
neptunium mononitride, azanylidyneneptunium, neptunium(III) nitride
Identifiers
3D model (JSmol)
  • InChI=1S/N.Np/q-3;+3
    Key: CONMGCPYTMDXHG-UHFFFAOYSA-N
  • [Np+3].[N-3]
Properties
NNp
Molar mass 251 g·mol−1
Appearance black crystals
Density 14.18 g/cm3
Melting point 2,557 °C (4,635 °F; 2,830 K)
insoluble
Except where otherwise noted, data are given for materials in their standard state (at 25 °C [77 °F], 100 kPa).
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Preparation

Neptunium nitride can be prepared by the reaction of freshly obtained neptunium hydride and ammonia:[3]

NpH3 + NH3 → NpN + 3H2

The reaction of neptunium and nitrogen can also obtain neptunium nitride:

Np + N2 → 2NpN

Physical properties

Neptunium nitride forms black crystals in the cubic system with Fm3m space group.[4][5] It is insoluble in water[6] and decomposes if heated.[7]

2NpN → 2Np + N2

Uses

Neptunium nitride is used as a target material for plutonium-238 production.[8]

237
93
Np
+
n
238
93
Np

References

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