Petalite
Silicate mineral, used in ceramic glazing From Wikipedia, the free encyclopedia
Petalite, also known as castorite, is a lithium aluminum phyllosilicate[7] mineral LiAlSi4O10, crystallizing in the monoclinic system. Petalite occurs as colorless, pink, grey, yellow, yellow grey, to white tabular crystals and columnar masses. It occurs in lithium-bearing pegmatites with spodumene, lepidolite, and tourmaline. Petalite is an important ore of lithium, and is converted to spodumene and quartz by heating to ~500 °C and under 3 kbar of pressure in the presence of a dense hydrous alkali borosilicate fluid with a minor carbonate component.[8] Petalite (and secondary spodumene formed from it) is lower in iron than primary spodumene, making it a more useful source of lithium in, e.g., the production of glass. The colorless varieties are often used as gemstones. [citation needed]
Petalite | |
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Petalite from Minas Gerais State, Brazil (size: 3x4 cm) | |
General | |
Category | Phyllosilicate |
Formula | LiAlSi4O10 |
IMA symbol | Ptl[1] |
Strunz classification | 9.EF.05 |
Crystal system | Monoclinic |
Crystal class | Prismatic (2/m) (same H-M symbol) |
Space group | P2/a |
Unit cell | a = 11.737 Å, b = 5.171 Å, c = 7.63 Å; β = 112.54°; Z = 2 |
Identification | |
Color | Colorless, grey, yellow, pink, to white |
Crystal habit | Tabular prismatic crystals and columnar masses |
Twinning | Common on {001}, lamellar |
Cleavage | Perfect on {001}, poor on {201} with 38.5° angle between the two |
Fracture | Subconchoidal |
Tenacity | Brittle |
Mohs scale hardness | 6–6.5 |
Luster | Vitreous, pearly on cleavages |
Streak | Colorless |
Diaphaneity | Transparent to translucent |
Specific gravity | 2.4 |
Optical properties | Biaxial (+) |
Refractive index | nα = 1.504, nβ = 1.510, nγ = 1.516 |
Birefringence | δ = 0.012 |
2V angle | 82–84° measured |
Melting point | 1350 °C[2] |
Fusibility | 5 |
Solubility | Insoluble |
References | [3][4][5][6] |
Discovery and occurrence
Petalite was discovered in 1800, by Brazilian naturalist and statesman Jose Bonifacio de Andrada e Silva. Type locality: Utö Island, Haninge, Stockholm, Sweden. The name is derived from the Greek word petalon, which means leaf, alluding to its perfect cleavage.[5][9][10]
Economic deposits of petalite are found near Kalgoorlie, Western Australia; Aracuai, Minas Gerais, Brazil; Karibib, Namibia; Manitoba, Canada; and Bikita, Zimbabwe.
The first important economic application for petalite was as a raw material for the glass-ceramic cooking ware CorningWare.[citation needed] It has been used as a raw material for ceramic glazes.
References
External links
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